Atomic Spectra and Atomic Structure (Dover Books on Physics)

Book Details

• Author: Gerhard Herzberg

• Publisher: Dover

• Edition: 2nd Edition

• Binding: Paperback

• Format: Illustrated

• Number of Pages: 288

• Release Date: 22-07-2010

• ISBN: 0800759601158

• Languages: English

• Package Dimensions: 8.0 x 5.4 x 0.5 inches

About The Book

Atomic Spectra and Atomic Structure by Gerhard Herzberg is widely regarded as one of the most comprehensive and accessible introductions to atomic spectra and their relationship to atomic structure. The book is particularly beneficial for physicists, physical chemists, and specialists in other fields who require a basic yet thorough understanding of atomic spectra due to their importance in various scientific applications.

The author focuses on the physical aspects of atomic spectra rather than heavy mathematics, making complex concepts more approachable. Herzberg uses experimental data to develop theoretical concepts, avoiding mathematical proofs but providing references for those interested in more detailed derivations.

Key Topics Covered:

1. Simplest Line Spectra and Elements of Atomic Theory

   • Empirical hydrogen terms and Bohr's theory of Balmer terms.

   • Energy level diagrams and the introduction to wave and quantum mechanics.

   • Alkali spectra and the spectrum of helium and alkaline earths.

2. Multiplet Structure of Line Spectra and Electron Spin

   • Explanation of empirical facts and quantum numbers.

   • Space quantization effects like the Zeeman and Stark effects.

3. Building-up Principle and Periodic System of Elements

   • Pauli's exclusion principle, electron configuration, and term determination.

   • The periodic system of elements.

4. Finer Details of Atomic Spectra

   • Intensities of spectral lines, series limits, and the interval rule.

   • Coupling of electrons and finer details of spectral analysis.

5. Hyperfine Structure of Spectral Lines

   • Effects of isotope shifts and nuclear spin.

6. Experimental Results and Applications

   • Ionization potentials, energy level diagrams, and magnetic susceptibility.

   • Chemical applications of atomic spectra.

With 80 illustrations and clear, accessible explanations, this book serves as an essential reference for both students and professionals seeking a comprehensive understanding of atomic spectra. It is particularly suited for those in fields where atomic spectra are significant but who may not be specialists in the area.